Product ID:EPA 525, 545.1 INTERNAL STANDARD MIX, 48242
MSDS Date:07/13/1993
FSC:6630
NIIN:00N066603
MSDS Number: BZSBL

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

PHENANTHRENE; (PHENANTHRENE-D10) (MFR CAS #1517-22-)

CAS: 85-01-8

RTECS: SF7175000

Fraction By Weight: 0.05%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACENAPHTHYLENE; (ACENAPHTHYLENE-D8, 1,2-DIDEUTERO,

CAS: 83-32-9

RTECS: AB1000000

Fraction By Weight: 0.05%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

CHRYSENE; (CHRYSENE D12) (MFR CAS #1719-03-)

CAS: 218-01-9

RTECS: GC0700000

Fraction By Weight: 0.05%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

(ORAL,RAT) 9750 MG/KG.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 99-100%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM;1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENT 4.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:BURNS EYES. IRRITATES RESPIRATORY
TRACT. CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. IRRITATES SKIN. DERMATITIS, HEADACHE, DIZZINESS,
GASTROINTESTINAL DISTURBANCES. DEPRESSE S CENTRAL NERVOUS SYSTEM.
CONVULSIONS, ERYTHEMA, ECZEMA, CONJUNCTIVITIS & CORNEAL EROSION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LST 15 MINS. CONT MD. SKIN:PROMPTLY
WASH W/MILD SOAP & LG VOLS OF WATER. REMOVE CONTAM CLTHG.
INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS, GIVE ARTF RESP. CONT
MD. INGEST:N EVER GIVE ANYTHING BY MOUTH TO UNCON PERS. NEVER TRY
TO MAKE UNCON PERS VOMIT. GIVE LG AMTS OF WATER. PRESS FINGERS TO
BACK OF TONGUE TO INDUCE VOMIT. IMMED CONTACT MD.

Flash Point Method:CC
Flash Point:-2F,-19C
Lower Limits:2.6%
Upper Limits:13%
Extinguishing Media:DRY CHEMICAL, ALCOHOL FOAM. WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS FORM EXPLOSIVE MIXTURES W/AIR.
CONTAINERS MAY EXPLODE UNDER FIRE CONDITIONS.

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM IGNITION SOURCES. AVOID EYE OR SKIN CONTACT. AVOID
BREATHING VAPORS.
Other Precautions:THIS MATL IS INTENDED FOR R&D USE ONLY & MAY NOT BE
USED FOR DRUG, HOUSEHOLD/OTHER PURPOSES. IN ADDN, BURDEN OF SAFE
USE OF MATL RESTS W/YOU & THEREFORE, IT SHOULD BE HNDLD ONLY BY
QUALIFIED PERS TRAI NED IN LAB PROCS & GOOD SFTY PRACTICES.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED SELF CONTAINED
BREATHING APPARATUS.
Ventilation:USE ONLY IN EXHAUST HOOD.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID:CHLORINATED COMPOUNDS.

Boiling Pt:B.P. Text:133F,56C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:181 @ 20C
Vapor Density:2
Spec Gravity:0.792 (H*2O=1)
Evaporation Rate & Reference:14.4 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:1

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES, OXIDIZING AGENTS, AMINES, OXYGEN,
ALKANOLAMINES, HALOGENS, ALDEHYDES, AMMONIA & (SUPP DATA)

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTIED. EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE: HANDLE AS IF
THEY WERE FULL.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.